[wordup] Scientists have managed to coax bacteria into producing hydrogen
Adam Shand
adam at shand.net
Mon Apr 25 19:16:49 EDT 2005
Via: Mike Messick <mikem at tridigitalenterprises....>
From: http://www.newindpress.com/NewsItems.asp?ID=IE320050424061423
Scientists overcome 'fermentation barrier'
Sunday April 24 2005 16:35 IST
LOS ANGELES: Scientists have managed to coax bacteria into producing
hydrogen - a development that would reduce the cost of waste water
treatment.
Using a little amount of electricity - about 0.25 volts - scientists at
Pennsylvania State University found that a microbial fuel cell can
overcome its "fermentation barrier", Xinhua reports.
The voltage is just one-tenth needed for electrolysis - the process
that uses electricity to break water down into hydrogen and oxygen.
"Basically, we use the same microbial fuel cell we developed to clean
waste water and produce electricity. However, to produce hydrogen, we
keep oxygen out of the microbial fuel cell and add a small amount of
power into the system," said Bruce Logan, a professor who led the
study.
In a paper "Electrochemically Assisted Microbial Production of Hydrogen
from Acetate", the researchers explained that hydrogen production by
bacterial fermentation was limited by "the fact that bacteria, without
a power boost, can only convert carbohydrates to a limited amount of
hydrogen - and a mixture of 'dead end' fermentation end-products such
as acetic and butyric acids".
The voltage to be given, scientists explain, is a small fraction of the
voltage needed to run a typical six-volt cell phone.
But it overcomes the "dead end" created during fermentation and
produces four times more hydrogen than would be typically generated by
fermentation alone.
Besides, the new process is not limited to using only
carbohydrate-based biomass. Theoretically, it yields hydrogen from any
biodegradable, dissolved, organic matter and cleans wastewater.
In the procedure, when the bacteria eat the biomass, they transfer
electrons to an anode. The bacteria also release protons - hydrogen
atoms stripped of their electrons - which go into solution.
Anode's electrons migrate via a wire to the cathode, the other
electrode in the fuel cell, where they are electrochemically assisted
to combine with protons to produce hydrogen gas.
The voltage is applied to the circuit by connecting the positive pole
of a programmable power supply to the anode and the negative pole to
the cathode.
The new process demonstrates, for the first time, the real potential in
capturing hydrogen from renewable sources.
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